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SHORT-TERM INTEREST RATES: 1900 1945 Table 49 lists short-term American interest rates from 1900 to 1945. It includes seven types of money-market rates: (a) prime four- to six-month commercial paper rates in terms of annual averages, monthly high averages, and monthly low averages; (b) prime sixty- to ninety-day commercial paper rates until 1936 in terms of annual averages; (c) call loan rates in terms of annual averages, monthly high and low averages, and

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Prior to the existence of transistorized circuitry, it was common to see vacuum tube testers in hardware stores, pharmacies, and electronics shops. Every home had replaceable tubes within, and tube shopping was a way of life. Tubes, as do light bulbs, age and eventually fail. The first symptom of tube failure in audio circuits was often an audible buzz or hum. The suspect tube was flicked with a fingernail. If the hum responded, the tube was verbally demeaned, removed from the socket, and escorted to the drug store. With luck, the tube would test to be bad and the shopkeeper would have a replacement on hand (maybe even stored inside the back of the tester). Those were the days of homefix circuits. Rejoice those days are not gone. Today, a likely culprit behind audio hum, buzz, or squeal is the capacitor. Especially canned capacitors, such as electrolytics.

9-63

9-64

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The former gives a mixture of the block copolymer with the two homopolymers since the polymer radicals combine randomly. The latter yields the block copolymer along with the homopolymer of M1 . Treatment of polyisobutylene (which contains terminal double bonds) with ozone followed by thermolysis produces polymeric radicals. Isobutylene styrene block copolymer is formed when thermolysis is performed in the presence of styrene, but the process is not ef cient because polystyrene and polyisobutylene homopolymers constitute more than half of the product [Cunliffe et al., 2001]. The synthesis of special initiators is another route to block copolymers. Reaction of XXXVI with an HO-terminated polyester or polyether yields a polymeric azonitrile, which initiates polymerization of a monomer such as styrene [Laverty and Gardland, 1977; Walz and Heitz, 1978].

THE UNITED STATES IN THE TWENTIETH CENTURY: 1900 1945

9-11

On the back side of the main circuit board, you ll find capacitor C39 near the far edge (see Figure 31-3). If your DH 100 is squealing, this is probably the culprit. It might even be leaking a fluid. You need to remove C39 from the board, clean the board, and replace C39 with a new capacitor. (C30 is also suspect if your DH 100 contains a C30 not all boards do; replace it too if replacing C39 does not solve the problem.)

The use of a polymer as a carrier or support for some component of a reaction system is discussed in the remainder of this chapter. Three classes of polymer supports are encountered polymer reagents, polymer catalysts, and polymer substrates [Kirschning et al., 2001; Sherrington, 2001]. Polymers that serve as reagents, catalysts, or substrates are functional polymers; that is, they contain a functional group that performs a particular chemical function. The term reactive polymer is also used. A polymer reagent is a polymer containing a functional group that acts as the reagent to bring about a chemical transformation on some small (i.e., low-molecular-weight) molecule. A polymer substrate has an attached molecule on which some transformation is carried out using a small-molecule reagent. A polymer catalyst contains a group that performs a catalytic function in some reaction usually a reaction between small molecules.

Table 49 Short-Term American Interest Rates: 1900 1945

There are two general approaches to the synthesis of a polymer reagent, catalyst, or substrate [Hodge, 1978; Mathur et al., 1980; Neckers, 1978; Sherrington, 1980, 1988]. In the functionalization of polymer approach the required functional group, which is to perform the reagent, catalyst, or substrate function, is attached to a readily available polymer by an appropriate reaction. The attachment is usually through a covalent bond, but ionic bonding has also been employed. In the functionalization of monomer approach an appropriate monomer with the desired functional group is synthesized and then polymerized or copolymerized.

9-11a-1

This approach can be illustrated by describing the preparation of the polymer rhodium catalyst II (Sec. 9-1g). The synthesis is based on a nucleophilic substitution reaction of chloromethylated polystyrene [Grubbs and Kroll, 1971]:

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