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With both new pots centered in their range and all new switches turned off, insert batteries and turn the instrument on. Play the DH 100 as usual, but experiment with the breath control against the pot settings. Slowly introduce your bending toggle switches and observe their effect upon the circuit. Touch the body-contacts and listen to the pitch and tone changes they induce. As always, check your wiring if anything seems wrong, or if the circuit ceases to function. Other than the squeal and often temperamental breath control, the DH 100 is rather hardy. If anything s not working properly, you can probably trace it to a bad solder connection and remedy things quickly.

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Long-maturity prime municipals reached a yield of only 090% at the 1946 highs; this represented a four-year price appreciation of about 21% Thus a bull market was superimposed on a bull market A price index of 4% thirty-year prime municipals (with constant maturity) had fluctuated over the years as follows.

(n+1)

9-61

Nonionic coupling reactions between appropriate polymers is another approach to graft copolymers. An example is the use of a telechelic polymer such as polystyrene containing one carboxyl end group per molecule. Graft copolymers are formed by coupling of carboxyl groups with the pendant epoxy groups of a copolymer of methyl methacrylate and glycidyl methacrylate [Miyauchi et al., 1988]. The carboxyl-terminated polystyrene can be obtained by living anionic polymerization followed by reaction with carbon dioxide or radical polymerization in the presence of a chain-transfer agent such as 3-mercaptopropionic acid.

Although the price advance from 1920 or from 1932 of good-quality, long-term, noncallable taxable bonds was less than the price advance of similar municipals, it was very considerable. Most corporate bonds had been called, or had defaulted, or had lost their credit standing. Those

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A telechelic polystyrene containing two carboxyl groups at one end of a polymer can be used as a macromonomer in a step polymerization with a diol or diamine to yield a polyester or polyamide containing graft chains of polystyrene. The required telechelic polymer is obtained by radical polymerization of styrene in the presence of 2-mercaptosuccinic acid. Macromonomers containing a norbornene group have been polymerized by ROMP (Sec. 7-8) to form graft copolymers [Breunig et al., 1995; Heroguez et al., 1997]. ROMP combined with living anionic polymerization produces an interesting architecture referred to as a double-brush polymer by using compound XXXII [R (CH2 10 OCH2 ], which contains both norbornene and 1,1-diphenylethylene (DPE) groups [Cheng et al., 2002]. ROMP of XXXII through the norbornene group produces a polymer (XXXIII) with pendant DPE groups. Reaction of XXXIII with living polystyryl anions produces XXXIV, a polymer with polystyrene graft chains. Subsequent reaction of XXXIV with monomer M2 (E-caprolactam, ethylene oxide, or hexamethylcyclotrisiloxane) yields the double-brush polymer XXXV, in which there is one brush of polystyrene graft chains and a second brush of polyM2 graft chains.

In contrast to many projects in this book, in which the bent instrument response is totally alien, the bent DH 100 still retains a strong degree of recognizable musicality. Although the bending switches introduce interesting pulses and stutters to the voice, and the dials bring forth varying overtones, envelopes, and textures, you re still playing the equal-tempered scale. You ve simply created a breath-controlled instrument that is no longer strapped to horn sounds. Instead, you re now playing a breath-controlled, who-knows-what synth from Mars, and that s all the fun.

9-62

few, mostly rails, that suffered none of these shortcomings served their owners well. A few examples are shown in the table below.

9-10

Most of the methods for synthesizing block copolymers were described previously. Block copolymers are obtained by step copolymerization of polymers with functional end groups capable of reacting with each other (Sec. 2-13c-2). Sequential polymerization methods by living radical, anionic, cationic, and group transfer propagation were described in Secs. 315b-4, 5-4a, and 7-12e. The use of telechelic polymers, coupling and transformations reactions were described in Secs. 5-4b, 5-4c, and 5-4d. A few methods not previously described are considered here. Block copolymers have been obtained from polymeric radicals, which unlike those employed for graft polymerization have the radical centers at the ends of the polymer chains. This can be achieved by breaking chemical bonds in the polymer backbone by mastication (mixing) of the polymer [Ceresa, 1973, 1976, 1978; Sakaguchi and Sohma, 1978]. If

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